Here's some reference links to parts of the WCF documentation that anyone interested in interoperability with WCF should find most useful.
Web Services Protocols Interoperability Guide
http://msdn2.microsoft.com/en-us/library/ms734776.aspx
Windows Communication Foundation (WCF) implements a number of Web Services Protocols. Many of these protocols include a number of options and extensibility points left to the discretion of the implementer to implement. This topic provides a list of Web Services Protocols implemented by WCF. Other topics within this section provide implementation details for each protocol supported.
Web Services Protocols Supported by System-Provided Interoperability Bindings in WCF
http://msdn2.microsoft.com/en-us/library/ms730294.aspx
Windows Communication Foundation (WCF) is built to interoperate with Web services that support a set of specifications known as the Web Services specifications. To simplify service configuration for interoperability best practices, WCF introduces three interoperable system-provided bindings: System.ServiceModel.BasicHttpBinding, System.ServiceModel.WsHttpBinding, and System.ServiceModel.WsDualHttpBinding. For metadata publication, there are two interoperable system-provided bindings: mexHttpBinding and mexHttpsBinding. This topic lists specifications that are supported by system-provided interoperable bindings.
wsHttpBinding
http://msdn2.microsoft.com/en-us/library/ms731299.aspx
Defines a secure, reliable, interoperable binding suitable for non-duplex service contracts. The binding implements the following specifications: WS-Reliable Messaging for reliability, and WS-Security for message security and authentication. The transport is HTTP, and message encoding is Text/XML encoding.
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